Asagiite

Asagiite
General
CategoryMineral sulphate
FormulaNiCu4(SO4)2(OH)6·6H2O
IMA symbolAsa
Strunz classification7.DD.
Crystal systemmonoclinic
Crystal class2/m-Prismatic
Identification
ColorPale blue-green
CleavagePerfect on {001}
Tenacitybrittle
Mohs scale hardness2.5
Lustervitreous
Streakwhite
Density2.90 g/cm3
Refractive index1.58,1.62,1.63
Birefringence0.054
2V angle52o

Asagiite is a rare hydrous nickel copper sulphate mineral, with the formula NiCu4(SO4)2(OH)6·6H2O. The mineral name was approved by the International Mineralogical Association in 2022, and the type description was published in 2023. It is isostructural with ktenasite, which has zinc in place of nickel.

Asagiite was first described from the Nakauri copper mine in Aichi prefecture, Japan, where it co-exists with the cobalt analogue of ktenasite, gobelinite. At this locality, platy crystals of asagiite are found as a secondary mineral in fractures in serpentinite, where they grow on aggregrates of smithsonite (ZnCO3). Asagiite has subsequently been confirmed from several other locations, including the Cap Garonne mines of France, which is the type locality of gobelinite.

The mineral is named for its light blue colour, which in Japanese is asagi-iro.

References

  1. 1 2 3 "Asagiite". Retrieved 17 October 2026 – via Mindat.org.
  2. 1 2 Nishio-Hamane, Daisuke; Yajima, Takeshi; Shimbayashi, Norimasa; Ohnishi, Masayuki; Niwa, Takefumi (2023). "Asagiite, NiCu4(SO4)2(OH)6·6H2O, a new member of the ktenasite group from the Nakauri mine, Shinshiro City, Aichi Prefecture, Japan". Journal of Mineralogical and Petrological Sciences. 118. doi:10.2465/jmps.230711.
  3. ↑ Favreau, Georges; Galéa-Clolus, Valérie (2024). "Cap Garonne 2014-2024, 10 ans de recherches minéralogiques". Le Cahier des Micromonteurs. 164: 5–176.