Gallium palladide

Gallium palladide
Names
	Preferred IUPAC name Gallium palladide
Identifiers
CAS Number	59125-32-5 ;
3D model (JSmol)	Interactive image;
ChemSpider	57529037;
PubChem CID	15162368;
CompTox Dashboard (EPA)	DTXSID90851987 ;
	InChI InChI=1S/Ga.Pd Key: OZTVKGRKOWIYRK-UHFFFAOYSA-N;
	SMILES [Ga].[Pd];
Properties
Chemical formula	GaPd
Molar mass	176.14 g·mol−1
Structure
Crystal structure	Iron monosilicide (cubic)
Space group	P213 (No. 198)
Lattice constant	a = 489.695 pm
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Gallium palladide (GaPd or PdGa) is an intermetallic combination of gallium and palladium. It has the iron monosilicide crystal structure. The compound has been suggested as an improved catalyst for hydrogenation reactions. In principle, gallium palladide can be a more selective catalyst since unlike substituted compounds, the palladium atoms are spaced out in a regular crystal structure rather than randomly.

References

↑ Armbrüster, Marc; Borrmann, Horst; Wedel, Michael; Prots, Yurii; Giedigkeit, Rainer; Gille, Peter (2010). "Refinement of the crystal structure of palladium gallium (1:1), PdGa" (PDF). Zeitschrift für Kristallographie - New Crystal Structures. 225 (4). Walter de Gruyter GmbH: 617–618. doi:10.1524/ncrs.2010.0269. ISSN 2197-4578. S2CID 98458695.
↑ Grin, Yu.; Armbrüster, M.; Baranov, A. I.; Finzel, K.; Kohout, M.; Ormeci, A.; Rosner, H.; Wagner, F. R. (2015-10-27). "Atomic interactions in the intermetallic catalyst GaPd". Molecular Physics. 114 (7–8). Informa UK Limited: 1250–1259. doi:10.1080/00268976.2015.1093664. ISSN 0026-8976. S2CID 102016870.
↑ Bhargava, M.K; Gadalla, A.A; Schubert, K (1975). "Koexistente phasen vom FeSi-Typ in den mischungen Ni-Pd-Ga und Ni-Pt-Ga". Journal of the Less Common Metals (in German). 42 (1). Elsevier BV: 69–76. doi:10.1016/0022-5088(75)90021-1. ISSN 0022-5088.
↑ OSSWALD, J; GIEDIGKEIT, R; JENTOFT, R; ARMBRUSTER, M; GIRGSDIES, F; KOVNIR, K; RESSLER, T; GRIN, Y; SCHLOGL, R (2008-08-15). "Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart I: Preparation and structural investigation under reaction conditions". Journal of Catalysis. 258 (1). Elsevier BV: 210–218. doi:10.1016/j.jcat.2008.06.013. hdl:11858/00-001M-0000-0010-FC1D-A. ISSN 0021-9517.
↑ OSSWALD, J; KOVNIR, K; ARMBRUSTER, M; GIEDIGKEIT, R; JENTOFT, R; WILD, U; GRIN, Y; SCHLOGL, R (2008-08-15). "Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart II: Surface characterization and catalytic performance". Journal of Catalysis. 258 (1). Elsevier BV: 219–227. doi:10.1016/j.jcat.2008.06.014. hdl:11858/00-001M-0000-0010-FC1A-0. ISSN 0021-9517.
↑ Armbrüster, Marc; Schlögl, Robert; Grin, Yuri (2014). "Intermetallic compounds in heterogeneous catalysis—a quickly developing field". Science and Technology of Advanced Materials. 15 (3) 034803. Informa UK Limited. Bibcode:2014STAdM..15c4803A. doi:10.1088/1468-6996/15/3/034803. ISSN 1468-6996. PMC 5090519. PMID 27877674.
↑ Krajčı´, M.; Hafner, J. (2012). "The (210) surface of intermetallic B20 compound GaPd as a selective hydrogenation catalyst: A DFT study". Journal of Catalysis. 295. Elsevier BV: 70–80. doi:10.1016/j.jcat.2012.07.025. ISSN 0021-9517.

This inorganic compound–related article is a stub. You can help Wikipedia by adding missing information.

[1] Armbrüster, Marc; Borrmann, Horst; Wedel, Michael; Prots, Yurii; Giedigkeit, Rainer; Gille, Peter (2010). "Refinement of the crystal structure of palladium gallium (1:1), PdGa" (PDF). Zeitschrift für Kristallographie - New Crystal Structures. 225 (4). Walter de Gruyter GmbH: 617–618. doi:10.1524/ncrs.2010.0269. ISSN 2197-4578. S2CID 98458695.

[2] Grin, Yu.; Armbrüster, M.; Baranov, A. I.; Finzel, K.; Kohout, M.; Ormeci, A.; Rosner, H.; Wagner, F. R. (2015-10-27). "Atomic interactions in the intermetallic catalyst GaPd". Molecular Physics. 114 (7–8). Informa UK Limited: 1250–1259. doi:10.1080/00268976.2015.1093664. ISSN 0026-8976. S2CID 102016870.

[3] Bhargava, M.K; Gadalla, A.A; Schubert, K (1975). "Koexistente phasen vom FeSi-Typ in den mischungen Ni-Pd-Ga und Ni-Pt-Ga". Journal of the Less Common Metals (in German). 42 (1). Elsevier BV: 69–76. doi:10.1016/0022-5088(75)90021-1. ISSN 0022-5088.

[4] OSSWALD, J; GIEDIGKEIT, R; JENTOFT, R; ARMBRUSTER, M; GIRGSDIES, F; KOVNIR, K; RESSLER, T; GRIN, Y; SCHLOGL, R (2008-08-15). "Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart I: Preparation and structural investigation under reaction conditions". Journal of Catalysis. 258 (1). Elsevier BV: 210–218. doi:10.1016/j.jcat.2008.06.013. hdl:11858/00-001M-0000-0010-FC1D-A. ISSN 0021-9517.

[5] OSSWALD, J; KOVNIR, K; ARMBRUSTER, M; GIEDIGKEIT, R; JENTOFT, R; WILD, U; GRIN, Y; SCHLOGL, R (2008-08-15). "Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart II: Surface characterization and catalytic performance". Journal of Catalysis. 258 (1). Elsevier BV: 219–227. doi:10.1016/j.jcat.2008.06.014. hdl:11858/00-001M-0000-0010-FC1A-0. ISSN 0021-9517.

[6] Armbrüster, Marc; Schlögl, Robert; Grin, Yuri (2014). "Intermetallic compounds in heterogeneous catalysis—a quickly developing field". Science and Technology of Advanced Materials. 15 (3) 034803. Informa UK Limited. Bibcode:2014STAdM..15c4803A. doi:10.1088/1468-6996/15/3/034803. ISSN 1468-6996. PMC 5090519. PMID 27877674.

[7] Krajčı´, M.; Hafner, J. (2012). "The (210) surface of intermetallic B20 compound GaPd as a selective hydrogenation catalyst: A DFT study". Journal of Catalysis. 295. Elsevier BV: 70–80. doi:10.1016/j.jcat.2012.07.025. ISSN 0021-9517.