In physics and representation theory, a phase factor is a multiplier representing the phase of a wave or the phase difference between two quantities. It is formulated as a unit complex number, that is a complex number with absolute value 1. For a complex number written in polar form, such as r eiθ, the phase factor is the complex exponential, eiθ,: 24 where the variable θ is the phase and i is the imaginary unit. If a quantity like a scalar, vector, or a matrix (representing a wave, state, or operator) is equal to another quantity times a phase factor, then those two quantities are said to be equivalent up to the phase factor, as it leaves the length (or norm) unchanged. As a set, the possible phase factors form the circle group , but the term often refers to a scalar recording a phase choice or convention, or an ambiguity in choosing a representative.
For a phase factor , the following hold:: 24
Multiplying the equation of a plane wave Aei(k·r − ωt) by a phase factor eiθ shifts the phase of the wave by θ: This phase factor is related to the arbitrary selection of the origin of the time axis.: 61
In quantum mechanics, a phase factor is a complex coefficient eiθ that multiplies a ket or bra . It does not, in itself, have any physical meaning, since the introduction of a phase factor does not change the expectation values of a Hermitian operator; this effect is known as phase ambiguity.: 108 That is, the values of and , where , are the same.
The phase ambiguity may also be described as a flexibility in the definition of quantum state functions. For example, the eigenfunctions of the angular momentum operator are uniquely defined "except for a phase factor".: 61
In defining spherical harmonics for use in quantum mechanics, the phase factor may be selected to have a standard value initially selected by Edward Condon and G.H. Shortley.: 61 For example, this convention is used for the Clebsch–Gordan coefficients.
Differences in phase factors between two interacting quantum states can sometimes be measurable, such as in the Berry phase,: 131 and the Aharonov-Bohm effect.: 231 In optics, the phase factor is an important quantity in the treatment of interference.
Phase factors can appear when a mathematical or physical object is determined only up to the choice of a representative. As noted above, in quantum mechanics, pure states are represented by rays in Hilbert space rather than by individual normalized vectors. Thus the physical states are normalized vectors up to a phase factor. Likewise, a symmetry of the ray space may be represented on Hilbert space by a unitary operator, but such an operator is determined only up to multiplication by a phase factor. Consequently, a symmetry group may act by operators satisfying where is a phase factor. Such an action is a projective representation.
A related ambiguity occurs in the representation theory of the Heisenberg group. Because of the Stone–von Neumann theorem, an automorphism of the underlying position-momentum space gives a unitary operator of the oscillator representation, but only up to a phase factor. The resulting operators therefore define a projective representation of the symplectic group. Passing to the metaplectic group resolves this ambiguity.