67 Oph has four companions. The closest is a magnitude 13.7 B1 main sequence star at 8.29", designated B. Component C (BD+02°3459) is the brightest close companion, a magnitude 8.1 B2 main sequence star at 54.32". Component D is a magnitude 12.5 star 8.37" from component C. Component E is a magnitude 10.9 star 46.53" from 67 Oph A.
This star was once considered part of the obsolete constellation Taurus Poniatovii, but after the International Astronomical Union officially recognized constellations, it was placed in Ophiuchus.
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Underhill, A. B. (1960). "Some spectroscopic observations of the supergiants 67 Ophiuchi, 55 Cygni and χ2 Orionis". Publ. Dominion Astrophys. Obs. 11: 353–361. Bibcode:1960PDAO...11..353U.