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Unlike Shelton's first three albums, which were all produced by Bobby Braddock, Pure BS features three different producers: Braddock, as well as Brent Rowan and Paul Worley.
The album's first single was "Don't Make Me", which peaked at number 12 on the Billboard country charts in 2007. Following this was the David Lee Murphy co-write "The More I Drink" which peaked at number 19. Pure BS was re-released in May 2008 as Pure BS Deluxe Edition. This re-issue included his cover of Michael Bublé's hit single "Home" and two additional tracks which Shelton wrote. The cover featured backing vocals from Miranda Lambert, whom Shelton would later marry. It was issued as a single in early 2008, and in July it became Shelton's fourth Number One single on the country charts.
"She Don't Love Me" was previously recorded by Trent Willmon on his self-titled debut album, and before that by Billy Ray Cyrus as "She Don't Love Me (She Don't Hate Me)" on his 2003 album Time Flies. It Ain't Easy Being Me" was originally recorded by the co-writer, Chris Knight on his 1998 self-titled debut album, and also covered by John Anderson on his 2001 album, Nobody's Got It All. "I Don't Care" was later reissued on Shelton's 2008 album, Startin' Fires.
