Selenide borate
List
name
chem
mw
crystal system
space group
unit cell
volume
density
comments
references
Zn8 Se2 [BO2 ]12
I 4 3m
a =7.6749 b= 7.6749 c= 7.6749
band gap 4.42 eV SHG 0.14xKDP
YSeBO2
210.68
orthorhombic
Cmc 21
a=5.6617 b=16.5858 c=1.441 Z=4
389.15
3.596
band gap 3.45 eV
Sm6 Ta2 MgSeB8 O26
1869.75
trigonal
P 3
a=8.089 c=8.6765 Z=1
491.70
6.314
Eu6 Ta2 MgSeB8 O26
1879.41
trigonal
P 3
a=8.0717 c=8.6491 Z=1
488.01
6.395
Gd6 Ta2 MgSeB8 O26
1911.15
trigonal
P 3
a=8.0536 c=8.6296 Z=1
484.73
6.547
References
↑ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (2020), CSD 1999764: Experimental Crystal Structure Determination , FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, doi :10.5517/ccdc.csd.cc253xjr , retrieved 2021-03-13
↑ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (October 2020). "Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis" . Journal of Solid State Chemistry . 290 121572. Bibcode :2020JSSCh.29021572Z . doi :10.1016/j.jssc.2020.121572 . S2CID 224876635 .
↑ Lu, Zhen-Tao; Fan, Wen-Jing; Wang, Zhi-Qian; Gu, Ning; Yue, Zeng-Hao; Xue, Huai-Guo; Guo, Sheng-Ping (2020-06-15). "Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO 2: Featuring a [ YSeBO 2 ] n Planar Belt" . Inorganic Chemistry . 59 (12): 7905– 7909. doi :10.1021/acs.inorgchem.0c00753 . ISSN 0020-1669 . PMID 32469211 . S2CID 218984948 .
1 2 3 Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE 6 Ta 2 MgQB 8 O 26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B 4 O 10 Cluster" . Inorganic Chemistry . 59 (6): 3532– 3536. doi :10.1021/acs.inorgchem.0c00086 . ISSN 0020-1669 . PMID 32090554 . S2CID 211263182 .
Salts and covalent derivatives of the
selenide ion