Tetravinyltin

Tetravinyltin
Names
	IUPAC name tetrakis(ethenyl)stannane
	Other names tetravinylstannane
Identifiers
CAS Number	1112-56-7 ;
3D model (JSmol)	Interactive image;
ChemSpider	25939952;
ECHA InfoCard	100.012.903
EC Number	214-193-6;
PubChem CID	66189;
CompTox Dashboard (EPA)	DTXSID7074450 ;
	InChI InChI=1S/4C2H3.Sn/c41-2;/h41H,2H2; Key: MZIYQMVHASXABC-UHFFFAOYSA-N;
	SMILES C=C[Sn](C=C)(C=C)C=C;
Properties
Chemical formula	C8H12Sn
Molar mass	226.894 g·mol−1
Appearance	Colorless liquid
Density	1.246 g/mL
Boiling point	160–163 °C (320–325 °F; 433–436 K)
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	Flammable, Toxic
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H226, H301, H311, H331
Precautionary statements	P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P310, P302+P352, P303+P361+P353, P304+P340, P311, P312, P321, P322, P330, P361, P363, P370+P378, P403+P233, P403+P235, P405, P501
Flash point	105 °F
Safety data sheet (SDS)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). (what is ?) Infobox references

Tetravinyltin (also known as tetravinylstannane) is an organotin compound with a chemical formula of C₈H₁₂Sn.

Uses

Upon heating, a mixture of tetravinyltin and tin tetrachloride undergo disproportionation to form divinyltin dichloride, vinyltin trichloride, and trivinyltin chloride in high yields. A study about this can be found in the Journal of American Chemical Society.

Tetravinyltin cannot be used for therapeutic or diagnostic purposes and must only be used for research. It can also be used for thin film deposition.

Hazards

According to the European Chemicals Agency, tetravinyltin is flammable in liquid and gas form. It is also toxic when in contact with skin, inhaled, and swallowed. Therefore, personal protective equipment must be used in handling and proper caution applied during use.

References

↑ PubChem. "Tetravinyltin". pubchem.ncbi.nlm.nih.gov. Retrieved 2021-04-21.
↑ "Tetravinyltin | Tetravinylstannane | Sn(CH=CH2)4". Ereztech. Retrieved 2021-04-21.
↑ Rosenberg, Sanders D.; Gibbons, Ambrose J. (1957-05-01). "The Disproportionation of Tetravinyltin with Tin Tetrachloride and the Cleavage of Some Vinyltin Compounds with Bromine". Journal of the American Chemical Society. 79 (9): 2138–2140. doi:10.1021/ja01566a029. ISSN 0002-7863.
↑ "Tetravinyltin | CAS 1112-56-7". www.scbt.com. Retrieved 2021-04-21.
↑ Elements, American. "Tetravinyltin". American Elements. Retrieved 2021-04-21.
↑ "Tetravinylstannane - Substance Information - ECHA". echa.europa.eu. Retrieved 2021-04-21.

External links

TETRAVINYLTIN - ChemicalBook
Tetravinylstannane at Encyclopedia of Reagents for Organic Synthesis
Stannane, tetraethenyl at NIST WebBook

[1] PubChem. "Tetravinyltin". pubchem.ncbi.nlm.nih.gov. Retrieved 2021-04-21.

[2] "Tetravinyltin | Tetravinylstannane | Sn(CH=CH2)4". Ereztech. Retrieved 2021-04-21.

[3] Rosenberg, Sanders D.; Gibbons, Ambrose J. (1957-05-01). "The Disproportionation of Tetravinyltin with Tin Tetrachloride and the Cleavage of Some Vinyltin Compounds with Bromine". Journal of the American Chemical Society. 79 (9): 2138–2140. doi:10.1021/ja01566a029. ISSN 0002-7863.

[4] "Tetravinyltin | CAS 1112-56-7". www.scbt.com. Retrieved 2021-04-21.

[5] Elements, American. "Tetravinyltin". American Elements. Retrieved 2021-04-21.

[6] "Tetravinylstannane - Substance Information - ECHA". echa.europa.eu. Retrieved 2021-04-21.