Vanadium

Vanadium, 23V
Vanadium
Pronunciation/vəˈneɪdiəm/ ​(və-NAY-dee-əm)
Appearanceblue-silver-grey metal
Standard atomic weight Ar°(V)
50.9415(1)
Vanadium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
–
↑
V
↓
Nb
titanium ← vanadium → chromium
Atomic number (Z)23
Groupgroup 5
Periodperiod 4
Block  d-block
Electron configuration[Ar] 3d3 4s2
Electrons per shell2, 8, 11, 2
Physical properties
Phase at STPsolid
Melting point2183 K ​(1910 °C, ​3470 °F)
Boiling point3680 K ​(3407 °C, ​6165 °F)
Density (near r.t.)6.11 g/cm3
when liquid (at m.p.)5.5 g/cm3
Heat of fusion21.5 kJ/mol
Heat of vaporization444 kJ/mol
Molar heat capacity24.89 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 2101 2289 2523 2814 3187 3679
Atomic properties
Oxidation states−3, −1, 0, +1, +2, +3, +4, +5 (an amphoteric oxide)
ElectronegativityPauling scale: 1.63
Ionization energies
  • 1st: 650.9 kJ/mol
  • 2nd: 1414 kJ/mol
  • 3rd: 2830 kJ/mol
  • (more)
Atomic radiusempirical: 134 pm
Covalent radius153±8 pm
Color lines in a spectral range
Spectral lines of vanadium
Other properties
Natural occurrenceprimordial
Crystal structure ​body-centered cubic (bcc)
Body-centered cubic crystal structure for vanadium
Speed of sound thin rod4560 m/s (at 20 °C)
Thermal expansion8.4 µm/(m⋅K) (at 25 °C)
Thermal conductivity30.7 W/(m⋅K)
Electrical resistivity197 nΩ⋅m (at 20 °C)
Magnetic orderingparamagnetic
Molar magnetic susceptibility+255.0×10−6 cm3/mol (298 K)
Young's modulus128 GPa
Shear modulus47 GPa
Bulk modulus160 GPa
Poisson ratio0.37
Mohs hardness6.7
Vickers hardness628–640 MPa
Brinell hardness600–742 MPa
CAS Number7440-62-2
History
DiscoveryAndrés Manuel del Río (1801)
First isolationHenry Enfield Roscoe (1867)
Named byNils Gabriel Sefström (1830)
Isotopes of vanadium
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
48V synth 16 d β+ 48Ti
49V synth 330 d ε 49Ti
50V 0.25% 2.71×1017 y ε 50Ti
β− 50Cr
51V 99.8% stable
 Category: Vanadium
| references
Vanadium

Vanadium is chemical element 23 on the periodic table. Its symbol is V. It is a metal and is part of the group known as the transition metals. It is gray-blue colored. It is mostly used in steel where it helps strengthen the steel metal. It is named after Vanadis, another name of Freyja.

Vanadium is often found in aquatic forms of life. The human body may need a little bit of vanadium, but scientists are not sure.

Vanadium can react with many other elements, and the chemical compounds it forms often have beautiful colors.

History

Vanadium was found for the first time in 1801 in Mexico by the Spanish mineralogist Andrés Manuel del Río in an ore called "brown lead". He named it panchromium because of the beautiful colors in its chemical compounds. He was told by other people that it was chromium and so he stopped researching it.

In 1831 Swedish chemist Nils Gabriel Sefström found the element in iron ores. The German chemist Friedrich Wöhler said it was the same element that del Río found in 1801. The element was then named vanadium.

Occurrence

The amount of vanadium in the Universe is 0.0001%, making the element almost as common as copper or zinc. Vanadium is detected by spectroscopy in light from the Sun, and sometimes in light from other stars.

Vanadium is the 22nd most common element in the Earth's crust. Metallic vanadium is rare in nature. Vanadium compounds occur naturally in about 65 different minerals. Most of the world's vanadium production comes from vanadium-bearing magnetite found in ultramafic gabbro rocks. Vanadium is mined mostly in South Africa, north-western China, and Eastern Russia. In 2013 these three countries mined more than 97% of the 79,000 tonnes of produced vanadium.

Vanadium is also in bauxite and in deposits of crude oil, coal, oil shale and tar sands.

Properties

Vanadium is soft compared to other metals. It is a good conductor of electricity and heat. It can be pulled out into wires (ductile). Pure vanadium will form a layer of vanadium oxide corrosion very fast.

Uses

A lot of vanadium (85%) is used to make different types of steel. Steel made with vanadium is stronger. It is also mixed with titanium to make metal alloys that are used in jet engines and tooth implants.

Vanadium is also used to make batteries.

In nature

Vanadium is used by several marine organisms. Some algae and bacteria (like Azotobacter) use it for nitrogen fixation.

References

  1. ↑ "Standard Atomic Weights: Vanadium". CIAAW. 1977.
  2. ↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  3. ↑ "Vanadium". Royal Society of Chemistry. Royal Society of Chemistry. Retrieved December 5, 2022.
  4. ↑ Cintas, Pedro (2004-11-12). "The Road to Chemical Names and Eponyms: Discovery, Priority, and Credit". Angewandte Chemie International Edition. 43 (44): 5888–5894. Bibcode:2004ACIE...43.5888C. doi:10.1002/anie.200330074. ISSN 1433-7851. PMID 15376297.
  5. 1 2 Rehder, Dieter 2008 (2008). Bioinorganic vanadium chemistry. Inorganic Chemistry (1st ed.). Hamburg, Germany: John Wiley & Sons, Ltd. pp. 5 & 9–10. doi:10.1002/9780470994429. ISBN 9780470065099.{{cite book}}: CS1 maint: numeric names: authors list (link)
  6. ↑ Cowley C.R. et al 1978 (1978). "Vanadium abundances in early A stars". Publications of the Astronomical Society of the Pacific. 90: 536. Bibcode:1978PASP...90..536C. doi:10.1086/130379. S2CID 121428891.{{cite journal}}: CS1 maint: numeric names: authors list (link)
  7. ↑ Ostrooumov M. and Taran Y. 2015. Discovery of native vanadium, a new mineral from the Colima Volcano, State of Colima (Mexico). Revista de la Sociedad Española de Mineralogía 20, 109-110
  8. ↑ "Vanadium: Vanadium mineral information and data". Mindat.org. Retrieved 2016-03-02.
  9. ↑ Magyar, Michael J. "Mineral Commodity Summaries 2015: Vanadium" (PDF). United States Geological Survey. Archived from the original (PDF) on 10 September 2015. Retrieved 3 June 2015.
  10. ↑ Rehder, Dieter (2019-12-18). "Vanadium: Biological, Environmental, and Engineering Aspects". Advances in Chemical Research. 2 (1): 1–23. doi:10.21926/acr.2001002. S2CID 214053167.